![]() ![]() An element consists of only one type of atom, which has a mass that is characteristic of the element and is the same for all atoms of that element ( Figure 2.2).An atom is the smallest unit of an element that can participate in a chemical change. Matter is composed of exceedingly small particles called atoms.Here are the postulates of Dalton’s atomic theory. First published in 1807, many of Dalton’s hypotheses about the microscopic features of matter are still valid in modern atomic theory. The Aristotelian view of the composition of matter held sway for over two thousand years, until English schoolteacher John Dalton helped to revolutionize chemistry with his hypothesis that the behavior of matter could be explained using an atomic theory. Interestingly, these philosophers thought about atoms and “elements” as philosophical concepts, but apparently never considered performing experiments to test their ideas. Later, Aristotle and others came to the conclusion that matter consisted of various combinations of the four “elements”-fire, earth, air, and water-and could be infinitely divided. In the fifth century BC, Leucippus and Democritus argued that all matter was composed of small, finite particles that they called atomos, a term derived from the Greek word for “indivisible.” They thought of atoms as moving particles that differed in shape and size, and which could join together. The earliest recorded discussion of the basic structure of matter comes from ancient Greek philosophers, the scientists of their day. State the postulates of Dalton’s atomic theory.Appendix L: Standard Electrode (Half-Cell) Potentialsīy the end of this section, you will be able to:.Appendix K: Formation Constants for Complex Ions.Appendix I: Ionization Constants of Weak Bases.Appendix H: Ionization Constants of Weak Acids.Appendix G: Standard Thermodynamic Properties for Selected Substances.Appendix F: Composition of Commercial Acids and Bases.Appendix D: Fundamental Physical Constants.Appendix C: Units and Conversion Factors.Second Law of Thermodynamics and Gibbs Free Energy.Application: Precipitation and Dissolution.Shifting Equilibria: LeChatelier’s Principle.Chemical Equilibria and Applications Toggle Dropdown Collision Theory and Factors Affecting Reaction Rates.Solutions and Colligative Properties Toggle Dropdown Liquids, Solids, and Modern Materials Toggle Dropdown Chemical Bonding and Molecular Geometry Toggle Dropdown Thermochemical Guidelines, Enthalpy of Formation and Hess's Law.Solution Stoichiometry and Combustion Analysis. ![]() Writing and Balancing Chemical Equations.Stoichiometry of Chemical Reactions Toggle Dropdown ![]()
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